Determination of polystyrene nanoparticles in aqueous solutions by the method of two-beam thermolens spectrometry

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Дәйексөз келтіру

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Рұқсат жабық Рұқсат берілді
Рұқсат жабық Тек жазылушылар үшін

Аннотация

Polymer micro- and nanoparticles (microplastics) are an environmental pollutant. The low content of microplastics in such objects can affect ecosystems and human health, therefore, there is a growing need to determine microplastic particles at a low content level and simultaneously assess the physico-chemical parameters of the systems under study. Thermolensing spectrometry (TLS) was used to determine polystyrene particles with sizes of 65 and 80 nm in the concentration range of 0.0005–0.15 mg/l in their aqueous dispersions. The comprehensive registration of the TL data also made it possible to evaluate the thermal conductivity of these solutions. It has been established that an increase in the content of polystyrene nanoparticles in water leads to a nonlinear change in thermal conductivity.

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Авторлар туралы

V. Khabibullin

Lomonosov Moscow State University

Хат алмасуға жауапты Автор.
Email: Vladhab1995@gmail.com
Ресей, Moscow, 119234

N. Shevchenko

High Molecular Compounds Institute of the Russian Academy of Sciences

Email: Vladhab1995@gmail.com
Ресей, Saint Petersburg

М. Proskurnin

Lomonosov Moscow State University

Email: Vladhab1995@gmail.com
Ресей, Moscow, 119234

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2. Fig. 1. Schematic diagram of the double-beam thermolens spectrometer.

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3. Fig. 2. Optical absorption spectra of polystyrene dispersions (without treatment) where: (a) sample MD-11, (b) MD-11-R, (c) MD-10, (d) MD-10-R.

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4. Fig. 3. Light scattering intensity for two types of microplastics at different mass concentrations measured with the additional detector of the thermolens spectrometer. Wavelength 633 nm, emission power 20 mW, measurement angle 90°.

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5. Fig. 4. Thermolens signal for dispersions of undyed polystyrene nanoparticles for mass (a) and absolute (b) concentrations. Wavelength 532 nm, emission power 300 mW, NP - nanoparticles.

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6. Fig. 5. Thermolens signal normalised to the degree of light-scattering radiation for undyed polystyrene nanoparticles. Wavelength 532 nm, emission power 300 mW.

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7. Fig. 6. Thermolens signal for dispersions of coloured polystyrene nanoparticles for mass (a) and absolute (b) concentrations. Wavelength 532 nm, emission power 300 mW, NP - nanoparticles.

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8. Fig. 7. Time-resolved curves for aqueous microplastic dispersions, where (a) are MD-10 series dispersions with 80 nm particle size and (b) are MD-11 series dispersions with 65 nm particle size, with different nanophase content. The wavelength is 532 nm and the emission power is 300 mW.

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9. Fig. 8. Time-resolved curves for polystyrene nanoparticle dispersions measured for 1 h and averaged from 2000 time-resolved curves. Wavelength 532 nm, irradiation power 300 mW.

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10. Fig. 9. Time-resolved curves for different types of polystyrene nanoparticles at different concentrations, where (a) MD-10-R, (b) MD-11-R. The wavelength is 532 nm and the emission power is 300 mW.

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11. Fig. 10. Temperature conductivity of polystyrene nanoparticle dispersions at different mass concentrations.

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