Effect of titanium silicate mineral natisite on gas transport properties of copolyimide P84

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Abstract

The development of membrane processes requires new materials for the production of highly efficient membranes. In this work, a composite based on P84 copolyimide with the additives of a new modifier of the titanosilicate mineral natisite was created. For this purpose, natisite was synthesized and identified. The P84/natisite composite (5 wt.%) prepared in a DMF solution was used to obtain a dense membrane. The features of the physicochemical, mechanical and gas transport properties of the P84/natisite membrane were studied in comparison with the P84 membrane. Transport properties were estimated by the permeability of He, O2, N2 and CO2 through the membranes. The value of gas permeability through the membranes made of the composite is lower compared to pure P84, and the selectivity of the separation of gas pairs H2/N2, CO2/N2 and O2/N2 is improved due to the inclusion of the natisite modifier. It has been shown that the introduction of 5 wt.% natisite additives does not have a significant effect on the physical and mechanical properties of the P84/natisite (5%) membrane, which meet the industrial requirements.

About the authors

A. E. Mukhin

Federal State Budgetary Educational Institution of Higher Education St. Petersburg State University

Email: a.pulyalina@spbu.ru

Institute of Chemistry

Russian Federation, St. Petersburg, 198504

G. A. Polotskaya

Federal State Budgetary Institution B.P.Konstantinov St. Petersburg Institute of Nuclear Physics of the Kurchatov Institute National Research Center

Email: a.pulyalina@spbu.ru

Institute of High Molecular Compounds

Russian Federation, St. Petersburg 199004

E. B. Ladanova

Federal State Budgetary Educational Institution of Higher Education St. Petersburg State University

Email: a.pulyalina@spbu.ru

Institute of Chemistry

Russian Federation, St. Petersburg, 198504

I. S. Kuryndin

Federal State Budgetary Institution B.P.Konstantinov St. Petersburg Institute of Nuclear Physics of the Kurchatov Institute National Research Center

Email: a.pulyalina@spbu.ru

Institute of High Molecular Compounds

Russian Federation, St. Petersburg 199004

V. N. Yakovenchuk

Kola Scientific Center of the Russian Academy of Sciences

Email: a.pulyalina@spbu.ru

Center for Nanomaterial Science, Geological Institute

Russian Federation, Apatity, 184209

G. O. Kalashnikova

Kola Scientific Center of the Russian Academy of Sciences

Email: a.pulyalina@spbu.ru

Center for Nanomaterial Science

Russian Federation, Apatity, 184209

A. Y. Pulyalina

Federal State Budgetary Educational Institution of Higher Education St. Petersburg State University; Kola Scientific Center of the Russian Academy of Sciences

Author for correspondence.
Email: a.pulyalina@spbu.ru

Institute of Chemistry, Center for Nanomaterial Science

Russian Federation, St. Petersburg, 198504; Apatity, 184209

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