| Dublin Core |
PKP Metadata Items |
Metadata for this Document |
| 1. |
Title |
Title of document |
Rhodamine 6G based molecular ion-active switches of optical and fluorescent properties |
| 2. |
Creator |
Author's name, affiliation, country |
E. N Shepelenko; Federal Research Centre the Southern Scientific Centre of the Russian Academy of Sciences |
| 2. |
Creator |
Author's name, affiliation, country |
V. A Podshibyakin; Institute of Physical and Organic Chemistry, Southern Federal University |
| 2. |
Creator |
Author's name, affiliation, country |
I. V Dubonosova; Institute of Physical and Organic Chemistry, Southern Federal University |
| 2. |
Creator |
Author's name, affiliation, country |
O. Yu. Karlutova; Institute of Physical and Organic Chemistry, Southern Federal University |
| 2. |
Creator |
Author's name, affiliation, country |
A. D Dubonosov; Federal Research Centre the Southern Scientific Centre of the Russian Academy of Sciences |
| 2. |
Creator |
Author's name, affiliation, country |
V. A Bren; Institute of Physical and Organic Chemistry, Southern Federal University |
| 3. |
Subject |
Discipline(s) |
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| 3. |
Subject |
Keyword(s) |
molecular switches; rhodamine 6G; fluorescence; chemosensors; ionochromic effect (naked-eye effect) |
| 4. |
Description |
Abstract |
A series of rhodamine 6G derivatives with o -hydroxyarylime substituents was synthesized. The obtained compounds in acetonitrile are capable of H+ induced transformation of the spirolactam form into open form. The process is accompanied by the formation of new long-wave absorption maxima at 527-529 nm and fluorescence bands at 557-560 nm. The compound containing 2-hydroxy-4-dimethylaminophenyl substituent in the presence of Zn2+ cations displays switching of emission at 429 nm. This fluorescence is quenched selectively by the CN- anion. Copper(II) cations cause the transformation of the spirostructure of rhodamine with a 2-hydroxy-3- tert -butylbenzofuran group into an open form. Isomerization occurs with a chromogenic naked-eye effect - a change in the color of the solution from pale yellow to pink and the appearance of fluorescence at 556 nm. The observed ion-induced spectral transformations can be used in design of optical and fluorescent chemosensors. |
| 5. |
Publisher |
Organizing agency, location |
ФИЦ КазНЦ РАН |
| 6. |
Contributor |
Sponsor(s) |
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| 7. |
Date |
(DD-MM-YYYY) |
15.08.2023
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| 8. |
Type |
Status & genre |
Peer-reviewed Article |
| 8. |
Type |
Type |
Research Article |
| 9. |
Format |
File format |
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| 10. |
Identifier |
Uniform Resource Identifier |
https://snv63.ru/0044-460X/article/view/666900 |
| 10. |
Identifier |
Digital Object Identifier (DOI) |
10.31857/S0044460X23080073 |
| 10. |
Identifier |
eLIBRARY Document Number (EDN) |
IXJEJN |
| 11. |
Source |
Title; vol., no. (year) |
Žurnal obŝej himii; Vol 93, No 8 (2023) |
| 12. |
Language |
English=en |
ru |
| 13. |
Relation |
Supp. Files |
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| 14. |
Coverage |
Geo-spatial location, chronological period, research sample (gender, age, etc.) |
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| 15. |
Rights |
Copyright and permissions |
Copyright (c) 2023 Russian Academy of Sciences
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